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Electrochemical properties of Langmuir-Blodgett films of polyesters derived from oligothiophenes

Identifieur interne : 017237 ( Main/Repository ); précédent : 017236; suivant : 017238

Electrochemical properties of Langmuir-Blodgett films of polyesters derived from oligothiophenes

Auteurs : RBID : Pascal:98-0223208

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English descriptors

Abstract

The electrochemical properties of polyesters derived from oligothiophenes have been studied in solution, and as Langmuir-Blodgett (LB) and cast films. Polyesters with four or five thiophene units exhibited a well-defined voltammetric response and good LB transfer characteristics. Mono and multilayer LB films were electroactive with clear symmetrical peaks, better developed than for the cast films. These films can be p- or n-doped electrochemically.

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Pascal:98-0223208

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<title xml:lang="en" level="a">Electrochemical properties of Langmuir-Blodgett films of polyesters derived from oligothiophenes</title>
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<name sortKey="Goldenberg, L M" uniqKey="Goldenberg L">L. M. Goldenberg</name>
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<s1>School of Engineering and Centre for Molecular Electronics, University of Durham</s1>
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<country>Royaume-Uni</country>
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<s1>Institute of Chemical Physics in Chernoglovka, Russian Academy of Science, CHernagolovka, 142432</s1>
<s2>Moscow</s2>
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<name sortKey="Donat Bouillud, A" uniqKey="Donat Bouillud A">A. Donat-Bouillud</name>
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<s1>Department of Chemistry, University of Montreal</s1>
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<sZ>3 aut.</sZ>
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<country>Angola</country>
<wicri:noRegion>Montreal, Que., H3C 3J7</wicri:noRegion>
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<name sortKey="Leclerc, M" uniqKey="Leclerc M">M. Leclerc</name>
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<s1>Department of Chemistry, University of Montreal</s1>
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<sZ>3 aut.</sZ>
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<country>Angola</country>
<wicri:noRegion>Montreal, Que., H3C 3J7</wicri:noRegion>
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<author>
<name sortKey="Petty, M C" uniqKey="Petty M">M. C. Petty</name>
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<title level="j" type="main">Journal of electroanalytical chemistry:(1992)</title>
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<term>Acetonitrile</term>
<term>Chemical solution</term>
<term>Disk electrode</term>
<term>Electrical conductor</term>
<term>Electrochemical properties</term>
<term>Ester polymer</term>
<term>Indium Oxides</term>
<term>Langmuir Blodgett layer</term>
<term>Optically transparent electrode</term>
<term>Organic solvent</term>
<term>Platinum</term>
<term>Thiophene derivative polymer</term>
<term>Tin Oxides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Propriété électrochimique</term>
<term>Conducteur électrique</term>
<term>Thiophène dérivé polymère</term>
<term>Ester polymère</term>
<term>Solution chimique</term>
<term>Couche Langmuir Blodgett</term>
<term>Electrode disque</term>
<term>Platine</term>
<term>Electrode optiquement transparente</term>
<term>Indium Oxyde</term>
<term>Etain Oxyde</term>
<term>Solvant organique</term>
<term>Acétonitrile</term>
<term>Electrode ITO</term>
<term>Ammonium(tétrabutyl) perchlorate</term>
<term>Thiophène(3-décyl) polymère</term>
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<term>Platine</term>
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<front>
<div type="abstract" xml:lang="en">The electrochemical properties of polyesters derived from oligothiophenes have been studied in solution, and as Langmuir-Blodgett (LB) and cast films. Polyesters with four or five thiophene units exhibited a well-defined voltammetric response and good LB transfer characteristics. Mono and multilayer LB films were electroactive with clear symmetrical peaks, better developed than for the cast films. These films can be p- or n-doped electrochemically.</div>
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<s1>Electrochemical properties of Langmuir-Blodgett films of polyesters derived from oligothiophenes</s1>
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<sZ>4 aut.</sZ>
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<sZ>1 aut.</sZ>
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<s1>Department of Chemistry, University of Montreal</s1>
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<sZ>3 aut.</sZ>
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<s0>CHE</s0>
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<s0>The electrochemical properties of polyesters derived from oligothiophenes have been studied in solution, and as Langmuir-Blodgett (LB) and cast films. Polyesters with four or five thiophene units exhibited a well-defined voltammetric response and good LB transfer characteristics. Mono and multilayer LB films were electroactive with clear symmetrical peaks, better developed than for the cast films. These films can be p- or n-doped electrochemically.</s0>
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<s0>001D09D04D</s0>
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<s5>01</s5>
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<s0>Electrochemical properties</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="GER">
<s0>Elektrochemische Eigenschaft</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA">
<s0>Propiedad electroquímica</s0>
<s5>01</s5>
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<s0>Conducteur électrique</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG">
<s0>Electrical conductor</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="GER">
<s0>Elektrischer Leiter</s0>
<s5>02</s5>
</fC03>
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<s0>Conductor eléctrico</s0>
<s5>02</s5>
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<s2>NK</s2>
<s5>03</s5>
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<fC03 i1="03" i2="X" l="ENG">
<s0>Thiophene derivative polymer</s0>
<s2>NK</s2>
<s5>03</s5>
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<s0>Tiofeno derivado polímero</s0>
<s2>NK</s2>
<s5>03</s5>
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<s0>Ester polymère</s0>
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<s5>04</s5>
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<s0>Ester polymer</s0>
<s2>NK</s2>
<s5>04</s5>
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<fC03 i1="04" i2="X" l="SPA">
<s0>Ester polímero</s0>
<s2>NK</s2>
<s5>04</s5>
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<s0>Solution chimique</s0>
<s5>06</s5>
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<s0>Chemical solution</s0>
<s5>06</s5>
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<s5>07</s5>
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<s0>Langmuir Blodgett layer</s0>
<s5>07</s5>
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<s0>Capa Langmuir Blodgett</s0>
<s5>07</s5>
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<s0>Electrode disque</s0>
<s5>09</s5>
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<s0>Disk electrode</s0>
<s5>09</s5>
</fC03>
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<s0>Electrodo disco</s0>
<s5>09</s5>
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<s0>Platine</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s5>10</s5>
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<s0>Platinum</s0>
<s1>ACT</s1>
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<s5>10</s5>
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<s2>NC</s2>
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<s1>ACT</s1>
<s2>NC</s2>
<s5>10</s5>
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<s5>12</s5>
</fC03>
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<s0>Optically transparent electrode</s0>
<s5>12</s5>
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<s0>Electrodo ópticamente transparente</s0>
<s5>12</s5>
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<fC03 i1="10" i2="X" l="FRE">
<s0>Indium Oxyde</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
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<s0>Indium Oxides</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
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<s0>Indio Óxido</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
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<fC03 i1="11" i2="X" l="FRE">
<s0>Etain Oxyde</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>14</s5>
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<fC03 i1="11" i2="X" l="ENG">
<s0>Tin Oxides</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>14</s5>
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<fC03 i1="11" i2="X" l="SPA">
<s0>Estaño Óxido</s0>
<s1>ACT</s1>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>14</s5>
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<s0>Solvant organique</s0>
<s5>16</s5>
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<s0>Organic solvent</s0>
<s5>16</s5>
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<s5>16</s5>
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<s5>16</s5>
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<s1>SOL</s1>
<s2>NK</s2>
<s5>17</s5>
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<s0>Acetonitrile</s0>
<s1>SOL</s1>
<s2>NK</s2>
<s5>17</s5>
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<s0>Acetonitrilo</s0>
<s1>SOL</s1>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Electrode ITO</s0>
<s4>INC</s4>
<s5>62</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Ammonium(tétrabutyl) perchlorate</s0>
<s1>SOL</s1>
<s2>NK</s2>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Thiophène(3-décyl) polymère</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>64</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Métal transition</s0>
<s2>NC</s2>
<s5>11</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Transition metal</s0>
<s2>NC</s2>
<s5>11</s5>
</fC07>
<fC07 i1="01" i2="X" l="GER">
<s0>Uebergangsmetalle</s0>
<s2>NC</s2>
<s5>11</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Metal transición</s0>
<s2>NC</s2>
<s5>11</s5>
</fC07>
<fN21>
<s1>145</s1>
</fN21>
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